Kinetics and Mechanism of Oxidation of D(+)-Sorbose by Chloramine-T
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چکیده
منابع مشابه
Kinetics and Mechanistic Study of Oxidation of Amoxicillin by Chloramine-t in Acid Medium
This spectroscopic study presents the kinetics and degradation pathways of oxidation of amoxicillin (AMOX) by chloramines-T (CAT) in acidic medium at a constant ionic strength of 0.105 mol dm-3 at 298 K. Reaction between AMOX and CAT in acidic medium exhibits 1:1 stoichiometry (AMOX:CAT). The reaction is of a first-order in both [CAT] and [AMOX]. The order with respect to acid concentration was...
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چکیده هدف از این کار بررسی الکترواکسیداسیون کتکول و مشتقات آن در حضور 4-فنیل سمی کاربامازید بوده است اکسیداسیون کتکولها ترکیبات نا پایدار کینونها را تولید می کنند که این ترکیبات می تواند در واکنش مایکل بعنوان پذیرنده نوکلئوفیل عمل نمایند. در ادامه اکسایش کتکولهای (a-c1) را درحضور 4-فنیل سمی کاربامازید در محلول آب/استونیتریل (90/10)بوسیله ولتامتری چرخه ای و کولن متری در پتانسیل ثابت مورد بررسی ...
15 صفحه اولOxidation of Some Aliphatic Aldehydes by Chloramine-t
Kinetic studies on the oxidation of acetaldehyde, propionaldehyde, nand tso-butyraldehyde have been made using diloramine-T as an oxidising agent in an alkaline medium. The reactions followed almost identical kinetics being first order with respect to both aldehyde and chloramine-T. The order with respect to alkali has been found to be almost equal to unity (0.8 to 0.90) . Effect of an increase...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1975
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.48.330